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Tanabe tanabe-sugano (ts) diagram
Tanabe Sugano (Ts) Diagram, supplied by Tanabe, used in various techniques. Bioz Stars score: 90/100, based on 1 PubMed citations. ZERO BIAS - scores, article reviews, protocol conditions and more
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Article Title: Magnetic coupling interaction-related photoluminescence behaviors in all-inorganic manganese chloride perovskites
Article Snippet: Manganese halides, as dilute magnetic semiconductor materials, have magnetic coupling interactions that play an essential role in their photoluminescence (PL); however, such interactions remain controversial.. AMnCl3 (AMC, A = K, Rb, and Cs) and their hydrates AMnCl3⋅2H2O (AMCH, A = K, Rb, and Cs) are both in the ABX3 configuration but exhibit a wide variety of structures with different connectivity types and dimensions.. Their magnetic coupling interaction has been demonstrated.

Article Title: Amino-Acid-Induced Circular Polarized Luminescence in One-Dimensional Manganese(II) Halide Hybrid.
Article Snippet: Circular polarized luminescence (CPL)-active materials attract great attentions owing to their widely applications in 3D optical displays and encrypted transmission.. Inspired by the strategies adopted in perovskite based CPL materials, herein, CPL-active hybrids (D)and (L)-(tert-butyl prolinate)MnCl3 were successfully prepared by assembling chiral D/L tert-butyl prolinate with manganese (II) chloride.. Single crystal structures show the as-formed hybrids possess one-dimensional (1D) structure containing linear chains of face-sharing MnCl6 octahedral surrounded by prolinate cations.

Article Title: Anti-thermal quenching and self-reduction characteristics in Mn2+-doped LiScGeO4: dual temperature effects on unique emission peak shifts
Article Snippet: Mn-doped phosphors exhibiting self-reduction behavior have garnered significant attention in the study of luminescent materials due to the defects generated during the self-reduction process and their unique luminescent behavior.. In this paper, LiScGeO4 red phosphors activated by the self-reduction of Mn4+ to Mn2+ were synthesized by high-temperature solid-state reaction in an air atmosphere.. The defects generated during the selfreduction process were leveraged to attain exceptional anti-thermal quenching characteristics, with luminescent intensity at a high temperature of 430 K being 1.23 times compared to that at room temperature of 300 K. In addition, a peculiar phenomenon occurred where the emission peak initially blueshifts and subsequently redshifts with the increasing temperature.

Article Title: Effects of High Pressure on the Bandgap and the d–d Crystal Field Transitions in Wolframite NiWO<sub>4</sub>
Article Snippet: The pressure effects on the optical and structural properties of NiWO4 have been studied experimentally and theoretically.. The fundamental bandgap decreases with a pressure coefficient of −12.0 ± 0.2 meV/GPa.. Meanwhile, the Ni2+ d−d transition energies increase at a rate of 7.4−14.8 meV/GPa.

Article Title: Recent progress on photoactive nonprecious transition-metal complexes
Article Snippet: CAS Key Laboratory of Photochemistry, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China; State Key Laboratory of Structural Cemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China; School of Chemistry and Chemical Engineering, Anhui Key Laboratory of Advanced Catalytic Materials and Reaction Engineering, Hefei University of Technology, Hefei 230009, China; State Key Laboratory of Explosion Science and Safety Protection, School of Mechatronical Engineering, Beijing Institute of Technology, Beijing 100081, China; College of Chemistry and Molecular Sciences, Hubei Key Lab on Organic and Polymeric Optoelectronic Materials, Wuhan University, Wuhan 430072, China; School of Chemistry and Chemical Engineering, Anhui University, Hefei 230601, China; Key Laboratory of Photochemical Conversion and Optoelectronic Materials & CAS-HKU Joint Laboratory on New Materials, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, China

Article Title: Synthesis and properties of blue zirconia ceramic based on Ni/Co doped Ba0.956Mg0.912Al10.088O17 blue pigments
Article Snippet: In this way, the assignments are consistent with the Tanabe-Sugano (TS) diagram for the d7 electron configuration in a tetrahedral crystal field (Fig. 7).

Article Title: A review on the advancements in the characterization of the high-pressure properties of iodates
Article Snippet: The d-d transition of the partially filled transition metal can be explained by the Tanabe-Sugano (TS) diagram [140], which is described by the crystal field energy Δ, and the inter-electronic repulsion interaction through Racah parameters B and C. According to the TS diagram for 3d7 ions, the ground state in the high spin is 4T1g(F), the spin allowed transition from the ground state to the other state are: 4T1g(F)→4T2g(F), 4T1g(F)→4A2g(F) and 4T1g(F)→4T1g(P).

Article Title: Efficient deep-red luminescence with high colour purity from Mn4+-doped ZnAl2O4 nanophosphor
Article Snippet: This work presents a highly intense deep-red luminescence (710–748 nm) from non-rare earth (Mn4+)-doped zinc aluminate (ZnAl2O4) nanophosphor.. The effect of different concentration of Mn (0.3–4%) on structural, morphological, optical properties and luminescence behaviour of ZnAl2O4 nanocrystals are investigated.. The Mn-doped ZnAl2O4 nanocrystals were prepared by microwave combustion method with annealing of the sample at 900 °C and characterized by different techniques.



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